You should use web3.js
I love PHP but it really suck with geth, geth itself hard and documentation sporadic and peoples know fews. I really got stuck building my whole app on php (generate wallet on register) then integrate web3.js in. Better you use only JS, a good example of a fabulous code is myetherwallet
From official web3.js doc:
https://github.com/ethereum/wiki/wiki/JavaScript-API#web3ethsendrawtransaction
var Tx = require('ethereumjs-tx');
var privateKey = new Buffer('e331b6d69882b4cb4ea581d88e0b604039a3de5967688d3dcffdd2270c0fd109', 'hex')
var rawTx = {
nonce: '0x00',
gasPrice: '0x09184e72a000',
gasLimit: '0x2710',
to: '0x0000000000000000000000000000000000000000',
value: '0x00',
data: '0x7f7465737432000000000000000000000000000000000000000000000000000000600057'
}
var tx = new Tx(rawTx);
tx.sign(privateKey);
var serializedTx = tx.serialize();
//console.log(serializedTx.toString('hex'));
//f889808609184e72a00082271094000000000000000000000000000000000000000080a47f74657374320000000000000000000000000000000000000000000000000000006000571ca08a8bbf888cfa37bbf0bb965423625641fc956967b81d12e23709cead01446075a01ce999b56a8a88504be365442ea61239198e23d1fce7d00fcfc5cd3b44b7215f
web3.eth.sendRawTransaction('0x' + serializedTx.toString('hex'), function(err, hash) {
if (!err)
console.log(hash); // "0x7f9fade1c0d57a7af66ab4ead79fade1c0d57a7af66ab4ead7c2c2eb7b11a91385"
});